Determination of the Characteristics of the Molecular Structure of Trialkyl Phosphates by the Joint Application of Electronic Ionization Mass Spectra with Registration of Positive Ions and Negative Ions of Resonance Coupling

Trialkylphosphates are of considerable interest from the military-chemical point view as precursors highly toxic organophosphorus toxicants, possible products their decontamination, complexing agents in processes reprocessing used nuclear fuel, etc. Meanwhile, development ways to identify these substances is still its infancy. In addition, trialkylphosphates an interesting subject for search a solution analytical problem establishing structure O-alkyl fragments molecules M(O) (OR) n esters multibasic acids, where M central atom (central core), basicity acid, R alkyl radicals with unknown and general case different number carbon atoms each them. No this could be found book sources. The aim work develop algorithm in-depth identification trialkyl phosphates, which includes belonging investigated substance class, well reliable method determining substances. On basis revealed regularities decay positive molecular ions negative resonant capture electrons same compound obtained under conditions electron ionization, phosphates proposed, molecule